Effects of H2O and CO2 diluted oxidizer on the structure and shape of laminar coflow syngas diffusion flames

The effects of up to 30% H2O and CO2 replacement of N-2 in air on the structure and shape of laminar coflow syngas (CO-H-2) diffusion flames were experimentally and numerically studied. Temperatures along the flame centerline were measured using a type-B thermocouple. The OH*-chemiluminescence and flame luminance were captured respectively by an intensified CCD camera and a CCD camera to determine the flame height and radii. The syngas diffusion flames were numerically modeled using detailed thermal and transport properties and the chemical reaction mechanism of Davis et al. (2005). Four pairs of artificial species were introduced in additional numerical calculations to isolate the chemical, thermal, transport, and radiative effects of H2O and CO2. The experimental and numerical results show that H2O and CO2 replacement of N-2 in the oxidizer reduce the peak flame temperature, but they influence the flame centerline temperature distributions differently. The thermal and radiative effects of both H2O and CO2 addition decrease the flame temperatures. The chemical and transport effects of CO2 and H2O affect flame temperatures differently. H2O addition promotes the OH concentration though H+O-2 =O+OH and O+H2O=2OH, while CO2 addition decreases the OH concentration by suppressing those reactions. The higher concentrations of OH under H2O addition signify higher combustion intensity and hence lead to decreased flame height and radius. In contrast, the addition of CO2 suppresses flame temperature and the overall combustion process, resulting in increased flame height and radius. (C) 2016 Published by Elsevier Inc. on behalf of The Combustion Institute.