Journal
ELECTROCHIMICA ACTA
Volume 229, Issue -, Pages 371-379Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.01.110
Keywords
Magnesium ion; aqueous battery; cathode material; magnesium manganese oxide; microsheet
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Funding
- National Natural Science Foundation of China [51672056]
- Natural Science Foundation of Heilongjiang Province of China [LC2015004]
- Fundamental Research Funds for the Central Universities [HEUCF20161002]
- Major Project of Science and Technology of Heilongjiang Province [GA14A101]
- Project of Research and Development of Applied Technology of Harbin [2014DB4AG016]
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Aqueous magnesium-ion batteries have shown the desired properties of high safety characteristics, similar electrochemical properties to lithium and low cost for energy storage applications. The micro sheet morphology of todorokite-type magnesium manganese oxide molecular sieve (Mg-OMS-1) material, which applies as a novel cathode material for magnesium-ion battery, is obtained by the simple hydrothermal method. The structure and morphology of the particles are confirmed by X-ray power diffraction, X-ray photoelectron spectroscopy, inductively coupled plasma, scanning and transmission electron microscopy. The electrochemical performance of Mg-OMS-1 is researched by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and constant current charge-discharge measurement. Mg-OMS-1 shows a good battery behavior for Mg2+ insertion and deinsertion in the aqueous electrolyte. When discharging at 10 mA g(-1) in 0.2 mol dm(-3) MgCl2 aqueous electrolyte, the initial discharge capacity reaches 300 mAhg(-1). The specific capacity retention rate is 83.7% after cycling 300 times at 100 mAg(-1) in 0.5 mol dm(-3) MgCl2 electrolyte with a columbic efficiency of nearly 100%. (C) 2017 Elsevier Ltd. All rights reserved.
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