Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 8, Pages 7331-7338Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b14638
Keywords
phenanthro[9,10-d]imidazole; donor acceptor emitter; high efficiency; high stability; deep-blue OLED
Funding
- Research Grants Council of the Hong Kong Special Administrative Region, China [T23-713/11]
- Guang-dong Innovative and Entrepreneurial Research Team Program [2013C090, KYPT20141013150545116]
- Natural Science Foundation of China [61575136, 21572152]
- Ministry of Science and Technology of China [2016YFB0401002]
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Organic materials containing arylamines have to been widely used as hole-transporting materials as well as emitters in organic light-emitting devices (OLEDs). However, it has been pointed out that the C-N bonds in these arylamines can easily suffer from degradation in excited states, especially in deep-blue OLEDs. In this work, phenanthro [9,10-d]imidazole (PI) is proposed as a potential donor with higher stability than those of arylamines. Using PI as the donor, a donor acceptor type deep-blue fluorophore 1-phenyl-2-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl-[1,1':4',1-terphenyl]-4-yl)1H-phenanthro[9,10-d]imidazole (BITPI) is designed and synthesized. Results from UV-aging test on neat films of BITPI and other three arylamine compounds demonstrate that PI is indeed a more stable donor comparing to common arylamines. An OLED using BITPI as an emitter exhibits good device performances (EQE over 7%) with stable deep-blue emission (color index: (0.15, 0.13)) and longer operation lifetime than the similarly structured device using arylamine-based emitter. Single-organic layer device based on BITPI also shows superior performances, which are comparable to the best results from the arylamine-based donor acceptor emitters, suggesting that PI is a stable donor with good hole transport/injection capability.
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