Journal
CHEMICAL REVIEWS
Volume 117, Issue 5, Pages 4528-4561Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00731
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Funding
- NIH-NIGMS [R01GM080269]
- Caltech
- Gordon and Betty Moore Foundation
- Margaret E. Early Medical Research Trust
- American Cancer Society [PF-16-011-01-CDD]
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Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.
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