Journal
CHEMSUSCHEM
Volume 10, Issue 5, Pages 842-846Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201601843
Keywords
cobalt; homogeneous catalysis; hydrogenation; nitrile; phosphines
Funding
- state of Mecklenburg-Vorpommern
- BMBF
- Ramon Areces Foundation
- LIKAT
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A general procedure for the catalytic hydrogenation of nitriles to primary amines by using a non-noble metal-based system is presented. Co(acac)(3) in combination with tris[2-(dicyclohexylphosphino) ethyl] phosphine efficiently catalyzes the selective hydrogenation of a wide range of (hetero) aromatic and aliphatic nitriles to give the corresponding amines.
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