Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 12, Pages 3360-3363Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611189
Keywords
batteries; guanidine; organic electron donors; oxidation; redox-active molecules
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
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The growing demand for efficient batteries has stimulated the search for redox-active organic compounds with multistage redox behavior, as materials with large charge capacity. Herein we report the synthesis and properties of the first hexakis(guanidino) benzene derivative: a strong neutral organic electron donor with reversible multistage redox behavior and a record low redox potential for donation of four electrons. Detailed structural and spectroscopic characterization of three redox states (0, + 2, and + 4) reveal its unique electronic features. Despite its nitrogen richness, the compound is thermally robust and can be readily purified by sublimation.
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