Journal
DALTON TRANSACTIONS
Volume 46, Issue 10, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00269f
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Funding
- Natural Science Foundation of China [107305-N11412]
- Chinese 1000 Young Talents Plan
- National Basic Research Program of China (973 Project) [2015CB856500]
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The regioselective derivatization of the monocarba-closo-dodecaborate anion via catalytic B-H bond activation is reported. Amide directing groups in combination with rhodium and iridium catalysts allowed for the direct functionalization of cage boron vertices. Products comprising B-C, B-N and B-Cl bonds were synthesized. As a key intermediate of the B-H activation step, an iridium complex with a direct B-Ir interaction was isolated and fully characterized by spectroscopic methods as well as X-ray crystallography.
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