Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 21, Pages 3058-3061Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10225e
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Funding
- Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-08ER46519]
- Department of Education Graduate Assistance in Areas of National Need (GAANN) Training Grant
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The first polymer-MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. With appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.
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