4.7 Article

Dynamic behaviours of a rationally prepared flexible MOF by postsynthetic modification of ligand struts

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 22, Pages 3220-3223

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00230k

Keywords

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Funding

  1. National Natural Science Foundation of China [11474204, 21271025, 21373027, 21673019]
  2. Research Foundation of Beijing Institute of Technology [20151942007]
  3. Beijing Nova Program [Z151100000315055]

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Through postsynthetic modification of ligand struts, controllable conversion of a Zr MOF between rigidity and flexibility is realized. The rationally prepared flexible MOF exhibits interesting dynamic behaviours, such as reversible structural deformation, vapour sorption hysteresis and unexpected adsorption of bulky guest molecules.

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