Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 6, Pages 658-661Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201600574
Keywords
allylation; aniline; catalysis; lanthanides; palladium
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Funding
- Agency for Science Technology and Research (AStar) [1321202095]
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The direct palladium catalyzed N-allylation of anilines by underivatized allyl alcohols can be achieved using lanthanide co-catalysis. The reaction works equally well with different lanthanides. Surprisingly, lanthanum acetate and lanthanum chloride can give yields comparable to or better than those obtained using lanthanum triflate. Electron-rich, unhindered anilines are the best substrates, although an aminopyridine and benzimidazole are both also efficiently allylated.
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