Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 11, Pages 1667-1673Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201700336
Keywords
aryl bromide; C-H functionalization; oxalic diamide; thioether; thiol
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Funding
- Ministry of Science and Technology, Taiwan [MOST 106-2113-M-005-001-]
- National Chung Hsing University
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We report the synthesis of thioether with high regioselectivity. The reaction proceeds through regioselective bromination followed by a copper/oxalic diamide-catalyzed C-S bond cross-coupling reaction. Functional groups, such as fluoro, chloro, trifluoromethyl, nitro, unprotected amine and pyridine, are tolerated by the reaction conditions.
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