Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 7, Pages 890-897Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201700173
Keywords
carbonylation; cross-coupling; green chemistry; heterocycles; oxidation
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Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi under the 12th five-year plan (FYP) project Affordable Cancer Therapeutics (ACT) [CSC0301]
- Science and Engineering Research Board (SERB), New Delhi under Start-up Grant for Young Scientists Scheme [SB/FT/CS-071/2014]
- International Scientific Partnership Program (ISPP) at King Saud University [ISPP0054]
- Commission (UGC)
- CSIR
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An efficient method for the oxidative cross-coupling of methylhetarenes with imidazoheterocycles by employing an eco-friendly iodine/DMSO reagent system has been developed. This C(sp(2))-H carbonylation reaction proceeds through an in situ oxidation of a methylhetarene into a formylhetarene followed by an oxidative cross-coupling reaction with an imidazoheterocycle. This method has a wide substrate scope and good functional group tolerance and enables the construction of a large number of carbonylated imidazoheterocycles in very good yields.
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