Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 12, Pages 1769-1772Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201700541
Keywords
allylic compounds; cyclopropanation; ketones; palladium; NHCs
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Funding
- National Natural Science Foundation of China (NSFC) [21532010, 21372242, 21472214, 21421091]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20030100]
- NSFC
- Research Grants Council of Hong Kong [21361162001]
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
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A Pd-catalyzed cyclopropanation reaction with aliphatic ketones as nucleophiles using a modified pyridine-NHC ligand was achieved. The reaction afforded the corresponding cyclopropanes in moderate to good yields with high cyclopropane/allylation selectivity.
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