Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 9, Pages 1510-1513Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09488k
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Funding
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG) [KR4782/2-1]
- University of Regensburg
- Stiftung Stipendien-Fonds des Verbands der Chemischen Industrie
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Using bis(beta-diketiminate) ligands we were able to synthesize unprecedented indium and thallium biscarbenoids. For indium, a novel four-membered metallacycle is derived from intra-and intermolecular In-In interactions in the solid state, while for thallium only an intramolecular Tl-2-pseudo-dimer is obtained. Computational studies revealed that the solid-state structures benefit significantly from dispersion stabilization.
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