Journal
CHEMSUSCHEM
Volume 10, Issue 6, Pages 1274-1282Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201601712
Keywords
aluminum; benchmarking; carbon dioxide; cyclic organic carbonates; homogeneous catalysis
Funding
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ-2014-60419-R, SEV-2013-0319]
- ICIQ
- ICREA Funding Source: Custom
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We report a comparative study on the activity of a series of fifteen binary catalysts derived from various reported aluminum-based complexes. A benchmarking of their initial rates in the coupling of various terminal and internal epoxides in the presence of three different nucleophilic additives was carried out, providing for the first time a useful comparison of activity metrics in the area of cyclic organic carbonate formation. These investigations provide a useful framework for how to realistically valorize relative reactivities and which features are important when considering the ideal operational window of each binary catalyst system.
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