Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 14, Pages 3916-3919Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700540
Keywords
boron; deep-ultraviolet; fluorooxoborates; nonlinear optical materials; second harmonic generation
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Deep-ultraviolet nonlinear optical (DUV NLO) crystals are the key materials to extend the output range of solid-state lasers to below 200 nm. The only practical material KBe2BO3F2 suffers high toxicity through beryllium and strong layered growth. Herein, we propose a beryllium-free material design and synthesis strategy for DUV NLO materials. Introducing the (BO3F)(4-),(BO2F2)(3-), and (BOF3)(2-) groups in borates could break through the fixed 3DB-O network that would produce a larger birefringence without layering and simultaneously keep a short cutoff edge down to DUV. The theoretical and experimental studies on a series of fluorooxoborates confirm this strategy. Li2B6O9F2 is identified as aDUV NLO material with a large second harmonic generation efficiency (0.9 x KDP) and a large predicted birefringence (0.07) without layering. This study provides a feasible way to break down the DUV wall for NLO materials.
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