Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 14, Pages 3920-3924Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201700679
Keywords
AC line-filtering; azulene; coordination polymers; layer-by-layer methods; micro-supercapacitors
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Funding
- 973 Programs of China [2013CBA01602]
- Natural Science Foundation of China [51403126]
- ERC Grant on 2DMATER
- UP-GREEN
- EU Graphene Flagship
- COORNET [SPP 1928]
- German Science Council, Center of Advancing Electronics Dresden [EXC1056, OR 349/1]
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On-chip micro-supercapacitors (MSCs) are important Si-compatible power-source backups for miniaturized electronics. Despite their tremendous advantages, current on-chip MSCs require harsh processing conditions and typically perform like resistors when filtering ripples from alternating current (AC). Herein, we demonstrated a facile layer-by-layer method towards on-chip MSCs based on an azulene-bridged coordination polymer framework (PiCBA). Owing to the good carrier mobility (5 x 10(-3) cm(2)V(-1) s(-1)) of PiCBA, the permanent dipole moment of azulene skeleton, and ultralow band gap of PiCBA, the fabricated MSCs delivered high specific capacitances of up to 34.1 Fcm(-3) at 50 mV s(-1) and a high volumetric power density of 1323 W cm(-3). Most importantly, such MCSs exhibited AC line-filtering performance (-73 degrees at 120 Hz) with a short resistance-capacitance constant of circa 0.83 ms.
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