4.8 Article

Sulfiphilic Nickel Phosphosulfide Enabled Li2S Impregnation in 3D Graphene Cages for Li-S Batteries

Journal

ADVANCED MATERIALS
Volume 29, Issue 12, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201603366

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Funding

  1. Joint Center for Energy Storage Research (JCESR), a battery hub under the US Department of Energy

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A 3D graphene cage with a thin layer of electrodeposited nickel phosphosulfide for Li2S impregnation, using ternary nickel phosphosulphide as a highly conductive coating layer for stabilized polysulfide chemistry, is accomplished by the combination of theoretical and experimental studies. The 3D interconnected graphene cage structure leads to high capacity, good rate capability and excellent cycling stability in a Li2S cathode.

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