Journal
DALTON TRANSACTIONS
Volume 46, Issue 8, Pages 2420-2424Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt04893e
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Funding
- Science and Engineering Research Board (SERB), India [SB/S1/IC-10/2014]
- CSIR, India
- MSM [CSC0129]
- DST [EMR/2014/000013]
- Ramanujan research grant [SB/S1/RJN-073/2014]
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The transition metal free catalytic hydroboration of aldehydes and ketones is very limited and has not been reported with a welldefined silicon(IV) compound. Therefore, we chose to evaluate the previously reported silicon(IV) hydride [PhC(NtBu)(2)SiHCl2], (1) as a single component catalyst and found that it catalyzes the reductive hydroboration of a range of aldehydes with pinacolborane (HBpin) under ambient conditions. In addition, compound 1 can catalyze imine hydroboration. DFT calculation was carried out to understand the mechanism.
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