Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 18, Pages 2701-2704Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00826k
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Funding
- Ministerio de Economia y Competitividad (MINECO) [CTQ201453695-P, CTQ2014-51912-REDC]
- Generalitat Valenciana [PROMETEO 2009/039, PROMETEOII/2014/017]
- University of Alicante
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The palladium(II)-catalyzed oxidation of homoallylic amine derivatives resulting from the allylation of N-tert-butanesulfinyl imines with allyl bromide led to the formation of the corresponding terminal allylic acetates in a regioselective fashion in moderate yields. In the case of the homoallylic amine derivatives obtained using cyclohexenyl bromide as the allylating reagent, the allylic oxidation took place with high regio- and diastereoselectivity and yields ranging from 40 to 85%.
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