Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 18, Pages 2737-2739Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10303k
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Funding
- Natural Science Foundation of Zhejiang Province [LQ15B020004]
- Natural Science Foundation of ZAFU [04251700011]
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An efficient iron(II)-catalyzed sulfur directedC(sp(3))-H bond amination/C-S cross coupling reaction has been developed. The reaction had high tolerance of functional groups under moderate conditions. The results of a deuterium labeling study and in situ ESI-MS experiments indicated that the reaction mechanism probably corresponds to a Fe(II)/Fe(III) catalytic cycle.
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