Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 10, Pages 1692-1695Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09261f
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Funding
- National Science Foundation [CHE-1465075]
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Most traditional photoreactions require UV light to yield the desired product. To address this issue, photoreaction of hydrazide based chromophores was evaluated with visible light using a metal free photocatalyst to afford photoproducts in high yields. This hydrazide functionality itself may be removed/modified after the photoreaction, highlighting its role as a photo-auxiliary''. A preliminary mechanistic model based on photophysical experiments is provided to highlight the generality of the strategy.
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