Journal
CRYSTENGCOMM
Volume 19, Issue 6, Pages 952-957Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce02363k
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Funding
- National Natural Science Foundation of China [51222207/E020802]
- 111 Project [B08040]
- Research Fund of State Key Laboratory of Solidification Processing (NWPU), China [142-TZ-2016]
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SiC nanonecklaces were synthesized on a large scale on as-prepared Si-SiC ceramic substrates via chemical vapor deposition with ferrocene as a catalyst. Structural, morphological, and elemental analyses showed that the as-synthesized nanonecklaces consisted of 3C-SiC stems up to several hundreds of micrometers in length with diameters of 200-400 nm, and SiO2 beads with diameters of 0.3-1 mu m. On the basis of the experimental and theoretical characterizations, a combination of growth mechanism of a vapor-liquidsolid-stem and modulation-bead was proposed as the growth mode of the SiC nanonecklaces.
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