Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 7, Pages 1313-1316Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09662j
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Funding
- Wuhan University [203273463]
- Youth Chen-Guang Science and Technology Project of Wuhan City [2015071704011640]
- Natural Science Foundation of Hubei Province [2014CFB181]
- 111'' Project of the Ministry of Education of China
- National Natural Science Foundation of China [21372179, 21432007, 21402145]
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An efficient rhodium-catalyzed asymmetric hydrogenation of alpha-amino acrylonitriles has been developed, affording alpha-acylamino nitriles with high yields and excellent enantioselectivities (up to 99% yield and >99% ee). This novel methodology provides an efficient and concise synthetic route to chiral alpha-amino nitriles, which are versatile intermediates in organic synthesis.
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