Journal
CERAMICS INTERNATIONAL
Volume 43, Issue 5, Pages 4023-4028Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2016.12.057
Keywords
Thermal batteries; Ceramic felt; Ionic conductivity; Electrochemical properties
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Funding
- Agency for the Defense Development of Korea [UD140074GD]
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In this Part 2, the ionic conductivity of molten salt electrolytes, the electrochemical properties of single cells containing a ceramic separator infiltrated with an electrolyte, and the mechanical strength of the electrolyte layer are compared with those of the conventional pellet-pressed structure. The ionic conductivity for the molten electrolyte is higher than that of the previous report for both LiCI-KCl and LiF-LiCl-LiBr electrolytes, which is explained by the decrease in contact resistance using a graphite electrode instead of stainless steel. The electrochemical performance of the single cells containing a ceramic felt separator assembled with Li(Si)/FeS2 electrodes shows longer operating time to a cut off voltage of 1.3 V compared to the conventional MgO-contained single cell. In addition, the flexural strength of the electrolyte layer with the ceramic felt separators is in the range of 2.80-6.29 kgf cm(-2), which is incomparable to that (=0.01 kgf cm(-2)) of the pellet-pressed conventional separator. These findings suggest that the ceramic felt separator can be an alternative to mitigate the current problems of pellet-pressed structure in thermal batteries, enhancing the mechanical strength and electrochemical properties.
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