Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 5, Issue 11, Pages 9657-9661Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b02855
Keywords
Cl resource; CO; Pd nanosalts; Polyketones; Seed-free polymerization
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Funding
- C1 gas refinery program [2015M3D3A1A01065436]
- National Research Foundation of Korea (NRF) [2017M1A2A2043141]
- National Research Foundation of Korea [2017M1A2A2043141] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Pd(II) nanosalts formed from [LnPd(OAc)(2)] [Ln = 1,3-]bis(di-o-methoxyphenylphosphino)propane) and ammonium tethered carboxylic acids in MeOH were utilized for the synthesis of antifouling polyketones from CO and olefin; this is the first instance of the synthesis of antifouling polyketones in the absence of additional heterogeneous seeds. The polymerization of CO and olefin achieved with the in situ-generated Pd(II) nanosalts was studied, and the nanosalts were analyzed by dynamic light scattering (DLS) experiments.
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