Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 5, Issue 12, Pages 11147-11162Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b02276
Keywords
NaOH; Caustic; Reverse osmosis; Bipolar membrane electrodialysis; Chlor-alkali; Electrolysis; Waste-to-resource; Circular economy
Categories
Funding
- Cadagua
Ask authors/readers for more resources
As global desalination capacity continues its rapid growth, the impetus for reducing the adverse environmental impacts of brine discharge grows concurrently. Although modern brine outfall designs have significantly limited such impacts, they are costly. Recovering valuable components and chemical derivatives from brine has potential to resolve both environmental and economic concerns. In this article, methods for producing sodium hydroxide (caustic) from seawater reverse osmosis (SWRO) brine for internal reuse, which typically involve brine purification, brine concentration, and sodium chloride electrolysis, are reviewed. Because process energy consumption drives process cost and caustic purity determines product usability in drinking water systems, reviewed technologies are benchmarked against thermodynamic minimum energy consumption and maximum (stoichiometric) NaOH production rates. After individual reviews of brine purification, concentration, and electrolysis technologies, five existing facilities for caustic production from seawater and seawater concentrates are discussed. Bipolar membrane electrodialysis appears to have the best potential to meet the technoeconomic requirements of small-scale caustic production from SWRO brine. Finally, future research and demonstration needs, to bring the technology to commercial feasibility, are identified.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available