Journal
CHEMISTRY OF MATERIALS
Volume 29, Issue 5, Pages 2135-2140Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.6b04745
Keywords
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Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2015R1A2A1A10055620, NRF-2016M1A2A2940911]
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The organic solar cell (OSC) performance of a series of new donor acceptor copolymers containing indolo[3,2b]indole as a key donor block and benzothiadiazole (BT) units with various degrees of fluorination as acceptors is reported. Compared with the simple carbazole unit, the strategically developed indolo[3,2-b]indole unit is found to significantly extend pi-conjugation and thus increase the intermolecular interactions of the resulting copolymer, as probed by density functional theory calculations, photophysical studies, and structural/morphological analyses. In addition, fluorination of BT can facilitate nano structuring of the copolymers, mainly due to further planarization of the backbone, which leads to apparently higher hole/electron charge carrier mobilities. The OSC properties of this series of new copolymers blended with fullerene show a strong dependence on the fine and continuous fibrous nanostructure of the blend film. The indolo[3,2-b]indole-based copolymer with singly fluorinated BT units possesses optimal intermolecular interactions and achieves the highest power conversion efficiency of 8.84% under AM 1.5G illumination. This result shows the potential of z-extended carbazole moieties for achieving high-performance OSCs with many of the favorable properties induced by large heteroacene blocks.
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