Journal
CHEMICAL SOCIETY REVIEWS
Volume 46, Issue 6, Pages 1675-1692Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cs00247a
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Funding
- NSFC [21372160, 21572135, 21125206, 21321061]
- Starting Foundation for Young Teachers of Sichuan University [2016SCU11009]
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The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two or more structurally and stereogenically different types of chiral products could be produced efficiently from an identical set of starting materials under readily tunable catalytic conditions, is one of the ultimate goals in asymmetric catalysis. This tutorial review will focus on the application of a variety of chiral organic catalysts, including Lewis bases, and Bronsted bases and acids, in a diverse range of stereoselective reactions in a switchable manner. Meanwhile, a few examples of divergent reactions through synergistic activation of organocatalysis and metal catalysis will also be discussed.
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