Journal
CRYSTENGCOMM
Volume 19, Issue 2, Pages 214-217Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce02281b
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Funding
- National Natural Science Foundation of China [21601137]
- Yunnan Applied Basic Research Projects [2016FD083]
- Scientific Research Foundation of the Education Department of Yunnan Province [2016ZZX229]
- Natural Science Foundation of Zhejiang Province [LQ16B010003]
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Two novel zinc-tetracarboxylate frameworks (FJI-8 and FJI-9) were solvothermally synthesized and structurally characterized. The 3D cage-stacking frameworks of FJI-8 and FJI-9 are each constructed of a truncated octahedral cage composed of {Zn-2{COO)(4)} paddlewheel SBUs and abtc(4-) ligands. Eight surrounding octahedral cages create an inner cuboctahedral cavity. In addition, both FJI-8 and FJI-9 exhibit tunable luminescence and white-light emission via varying the excitation wavelength.
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