Journal
CHEMISTRY LETTERS
Volume 46, Issue 4, Pages 434-437Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.161153
Keywords
Ionic liquid; Palladium(II) extraction; Platinum group metal (PGM)
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Management Expenses Grants for National Universities Corporations
- Grants-in-Aid for Scientific Research [16H04190] Funding Source: KAKEN
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Ionic liquids (ILs) bearing tetrahydropyran-2H-yl (THP)-protected thiol moieties were designed and synthesized as extractants for Pd(II)-selective extraction into an IL phase from a mixed aqueous HCl solution of Pd(II) and Pt(IV) salts. (HNMR)-H-1 measurements revealed that metal-selective THP-deprotection by the Pd(II) salt played a critical role to introduce the Pd(II)-selective extraction ability.
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