Journal
MATERIALS
Volume 10, Issue 4, Pages -Publisher
MDPI
DOI: 10.3390/ma10040444
Keywords
phase change material; thermal energy storage; latent heat storage; salt hydrate; sugar alcohol; properties; waste heat; DSC; thermal diffusivity; density
Categories
Funding
- German Federal Ministry for Economic Affairs and Energy (BMWi) [03ESP227B]
- German Research Foundation (DFG)
- University of Bayreuth
Ask authors/readers for more resources
The application range of existing real scale mobile thermal storage units with phase change materials (PCM) is restricted by the low phase change temperature of 58 degrees C for sodium acetate trihydrate, which is a commonly used storage material. Therefore, only low temperature heat sinks like swimming pools or greenhouses can be supplied. With increasing phase change temperatures, more applications like domestic heating or industrial process heat could be operated. The aim of this study is to find alternative PCM with phase change temperatures between 90 and 150 degrees C. Temperature dependent thermophysical properties like phase change temperatures and enthalpies, densities and thermal diffusivities are measured for the technical grade purity materials xylitol (C5H12O5), erythritol (C4H10O4) and magnesiumchloride hexahydrate (MCHH, MgCl2 center dot 6H(2)O). The sugar alcohols xylitol and erythritol indicate a large supercooling and different melting regimes. The salt hydrate MgCl2 center dot 6H(2)O seems to be a suitable candidate for practical applications. It has a melting temperature of 115.1 +/- 0.1 degrees C and a phase change enthalpy of 166.9 +/- 1.2 J/g with only 2.8K supercooling at sample sizes of 100 g. The PCM is stable over 500 repeated melting and solidification cycles at differential scanning calorimeter (DSC) scale with only small changes of the melting enthalpy and temperature.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available