Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 77, Issue -, Pages 58-61Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2017.02.013
Keywords
Na battery; Polymer electrolyte; Polycarbonate; Prussian blue
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Funding
- Stiftelsen Langmanska Kulturfonden
- Chemistry Research Centre (FCT) of the University of Minho [UID/QU1/00686/2013, UID/QUI/0686/2016]
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This paper describes the first implementation of the aliphatic polycarbonate PTMC- that has previously been successfully applied to lithium polymer batteries- as a non-polyether host matrix in solid-state sodium batteries. Despite higher glass transition temperatures of PTMC-NaTFSI and PTMC-NaClO4 electrolytes than their Li-containing counterparts, the ionic conductivities were found to be similar to the equivalent Li salt electrolytes. Finally, the functionality of PTMC-NaTESI was demonstrated through cycling of Na/Prussian blue half-cells displaying high discharge capacities and limited polarization at C/10 and 60 degrees C. (C) 2017 Elsevier By. All rights reserved.
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