Journal
CHEMISTRY LETTERS
Volume 46, Issue 4, Pages 412-422Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.161044
Keywords
Rechargeable lithium and sodium battery; Oxide ion redox; Charge compensation mechanism
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Funding
- Advanced Low Carbon Technology Research and Development Program of the Japan Science and Technology Agency (JST) Special Priority Research Area Next-Generation Rechargeable Battery
- MEXT program Elements Strategy
- MEXT program Elements Strategy Initiative to Form Core Research Center, MEXT
- Ministry of Education Culture, Sports, Science and Technology, Japan
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Research interest for a solid-state redox reaction of oxide ions (oxygen) is rapidly increasing for rechargeable battery applications. This article reviews the history and development of charge compensation mechanisms with oxide ions for electrode materials of batteries. Reversible and irreversible processes are observed after the oxidation of oxide ions, and it highly depends on the natures of chemical bonds between transition metals and oxide ions. Future possibility of high-energy lithium/sodium batteries with the oxide ion redox is also discussed.
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