Journal
ELECTROCHIMICA ACTA
Volume 232, Issue -, Pages 106-113Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.02.096
Keywords
Prussian blue; one-step synsthesis; K-ion capacitor; activated carbon; electrochemical behavior
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Funding
- National Materials Genome Project [2016YFB0700600]
- Natural Distinguished Youth Scientists Project of China [51425301, U1601214]
- Sanyo Chemical Co. Ltd., Japan
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Cubic Prussian blue (PB) crystals are prepared by a facile one-step synsthesis. The structure and morphology of the as-prepared samples are characterized by X-ray power diffraction, inductively coupled plasma, scanning electron microscopy and electrochemical measurement. The PB electrode exhibits superior electrochemical behavior in K2SO4 aqueous solution including high reversible capacity (80 mAh g(-1) at the current density of 0.5 A g(-1)), outstanding rate capability and good cycling stability. The K-ion capacitor (KIC) is also fabricated by using PB as a positive electrode and commercial activated carbon as an negative electrode, and it presents a maximum energy density of 28 Wh kg(-1) at the current density of 1 A g(-1) (corresponding to 7.5 mA cm(-2)). Furthermore, the KIC also exhibits excellent cycling stability at the current density of 2 A g(-1) with capacity retention of nearly 98% over 1200 cycles. Our synthesized electrode material provides a new way for fabricating high performance electrode materials for superior KIC. (C) 2017 Elsevier Ltd. All rights reserved.
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