Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 26, Pages 3685-3688Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01157a
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Funding
- Leverhulme Trust [RPG-2013-079]
- EPSRC [EP/K018388/1, EP/H003797/2]
- Engineering and Physical Sciences Research Council [EP/H003797/2, EP/H003797/1, EP/K018388/1, EP/I500987/1] Funding Source: researchfish
- EPSRC [EP/H003797/1, EP/I500987/1, EP/K018388/1, EP/H003797/2] Funding Source: UKRI
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Non-thermal plasmas were used as radical initiators in three radical chain reactions: dehalogenation, 5-exo-trig cyclisation and trifluoro-methylation with the Togni II reagent. The use of non-volatile solvents (or solvent-free conditions) gave high yields in all reactions under optimised conditions. Short reaction times and mild conditions make this method an attractive alternative to conventional radical initiators.
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