Oxidative Polyoxometalates Modified Graphitic Carbon Nitride for Visible-Light CO2 Reduction

Developing a photocatalysis system for converting CO2 to valuable fuels or chemicals is a promising strategy to address global warming and fossil fuel consumption: Exploring photocatalysts with high-performance and low -,cost has been two ultimate goals toward photoreduction of CO2. Herein, noble -Metal -free polyoxometalates :(Co-4) with oxidative ability was first introduced into g-C3N4 resulted in inexpensive hybrid materials (Co-4@g-C3N4) with staggered band alignment. The staggered composited' materials show a higher activity of CO, reduction than bare g-C3N4. An optimized CO4@g-C3N4 hybrid sample exhibited a high yield (107 mu mol g(-1) h(-1)) tinder visible -light irradiation (lambda >= 420 nm), meanwhile maintaining high selectivity for CO production (94%). After 10 h of irradiation, the production of CO reached 896 mu mol g(-1). Mechanistic studies revealed the introduction of Co4 not only facilitate the charge transfer of g-C3N4 but greatly increased the surface catalytic oxidative ability. This work creatively combined g-C3N4 with oxidative polyoxometalates which provide novel insights irito 'the design of low -Cost photocatalytic materials for CO2 reduction.