Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 20, Pages 4330-4334Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500487
Keywords
tert-Butanesulfinamide; Glycosylamines; Grignard reaction; Asymmetric synthesis; Glycosides
Categories
Funding
- Centre National de la Recherche Scientifique (CNRS)
- Labex SynOrg [ANR-11-LABX-0029]
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A study of the preparation and of the reactivity of N-tertbutanesulfinyl glycosylamines is reported for the first time. As they react readily as latent imine equivalents with a variety of carbon nucleophiles, these new carbohydrate derivatives constitute very useful precursors for the diastereoselective synthesis of bioactive compounds such as iminosugar-C-glycosides.
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