Journal
DALTON TRANSACTIONS
Volume 46, Issue 13, Pages 4170-4173Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt00185a
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Funding
- National Natural Science Foundation of China [51502307, 51402316, 61138004]
- National Key R& D Program of China [2016YFB0402103]
- National Instrumentation Program [2012YQ120048]
- Foundation of the Director of Technical Institute of Physics and Chemistry, CAS
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Hydrothermally grown iodate, K8Ce2I18O53, featuring polar 0D [Ce(IO3)(8)] (4-) units, has shown the highest visible light driven (VLD) photocatalytic activity in metal iodates reported before. The enhanced VLD photocatalytic property results from a synergistic effect between the narrow band gap and polar 0D [Ce(IO3)(8)](4-)units, as confirmed using first principles calculations.
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