Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 27, Pages 3894-3897Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10256e
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- CSIR
- CSIR-THUNDER [BSC 0102]
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Addition of arylboronic acids to directing group tethered acetylenes in a regio and stereoselective manner using an inexpensive catalytic system is achieved for the first time to access highly sought after allyl/homoallyl alcohol/amine units. The apparent vinylnickel intermediate was successfully trapped by the Michael electrophiles to get defined tri-and tetra-substituted olefins. An interesting selectivity switch was observed with internal alkynes.
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