4.7 Article

The role of weak interactions in controlling the mode of interpenetration in hybrid ultramicroporous materials

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 28, Pages 3978-3981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10217d

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Funding

  1. Science Foundation Ireland [13/RP/B2549]
  2. Science Foundation Ireland (SFI) [13/RP/B2549] Funding Source: Science Foundation Ireland (SFI)

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The aromatic core in dipyridyl linker ligands is found to impact the mode of 2-fold interpenetration in hybrid ultramicroporous materials formed by pillared square grid networks. An analysis of the crystal structures suggests that linker conformation and weak interactions between the linkers in adjacent networks might explain this phenomenon.

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