4.7 Article

Study of optimal parameters of the H2O2/O3 method for the decomposition of acetic acid

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 313, Issue -, Pages 309-316

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2016.12.040

Keywords

Advanced oxidation process; Acetic acid; Hydrogen peroxide; Ozone; Reaction model; Total organic carbon

Funding

  1. JSPS KAKENHI [26249032]
  2. Grants-in-Aid for Scientific Research [26249032] Funding Source: KAKEN

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Advanced oxidation processes (AOPs) constitute one of the most effective methods to decompose persistent organic pollutants in water using OH radicals. In this study, the parameters of the H2O2/O-3 method in the decomposition of acetic acid were investigated through a combination of experiments and numerical simulations. A simplified reaction model was built based on the analysis of the decomposition path. The simulation results showed that effective treatment of acetic acid can be achieved when the H2O2 supply rate is half of the O-3 absorption rate as one H2O2 and two O-3 molecules are necessary to produce two OH radicals. (C) 2016 Elsevier B.V. All rights reserved.

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