Journal
CHEMCATCHEM
Volume 9, Issue 5, Pages 728-732Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201601261
Keywords
hydrides; hydrogen transfer; oxidation; P ligands; palladium
Categories
Funding
- Centre National de la Recherche Scientifique (CNRS)
- Ministere de l'Enseignement superieur et de la Recherche (MESR)
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Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd-catalyzed oxidation of alcohols by a hydrogen-abstracting methodology. SPOs were found to promote the hydrogen-abstraction step as well as hydrogen transfer to a Michael acceptor by generating a putative active H-Pd species. The catalytic system operates under neutral conditions and was proven to be compatible with various electrophilic and nucleophilic functionalities within the substrates as well as water-and air-sensitive functional groups.
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