Journal
CHEMCATCHEM
Volume 9, Issue 6, Pages 1032-1039Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201601362
Keywords
allylic compounds; carbocations; graphene; green chemistry; rearrangement
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Funding
- University of Alicante [UAUSTI16-03, VIGROB-173]
- Spanish Ministerio de Economia y Competitividad [CTQ2015-66624-P]
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Graphene oxide (GO) and carboxylic acid functionalized GO (GO-CO2H) have been found to efficiently promote the heterogeneous and environmentally friendly pinacol rearrangement of 1,2-diols and the direct nucleophilic substitution of allylic alcohols. In general, high yields and regioselectivities are obtained in both reactions using 20 wt% of catalyst loading and mild reaction conditions.
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