Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 12, Pages 2579-2584Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500116
Keywords
C-H activation; Cross-coupling; Dihydrobenzofuran; Domino reactions; Mizoroki-Heck reaction; Palladium
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Funding
- National Natural Science Foundation of China [21202104]
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A palladium-catalyzed domino Mizoroki-Heck/intermolecular unactivated C(sp(3))-H alkylation reaction has been developed. This simple palladium nanoparticle catalytic system shows good activity and affords the dimeric dihydrobenzofuran derivatives in moderate to good yields. Furthermore, this reaction provides a new method for the elaboration of domino reactions involving a C(sp(3))-C(sp(3)) bond-forming process.
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