A highly sensitive and selective visible-light excitable luminescent probe for singlet oxygen based on a dinuclear ruthenium complex

A dinuclear Ru(II) complex of [(bpy)(2)Ru(H(2)ipaip)Ru(bpy)(2)] Cl-4 {bpy = 2,2'-bipyridine, H(2)ipaip = 2-(9-(1Himidazo[4,5-f][1,10] phenanthrolin-2-yl) anthracen-10-yl)-1H-imidazo[4,5-f][1,10] phenanthroline} is newly synthesized and characterized. Singlet oxygen sensing and ground-and excited-state acid-base properties of this complex are studied. The results indicated that the complex acted as a highly sensitive and selective luminescent probe for singlet oxygen (O-1(2)) in neutral and alkaline aqueous media under visible light excitation at 458 nm, resulting in 5.2-and 7.6-fold emission enhancement, respectively. This probe has advantages of visible light excitation, low singlet oxygen detection limits of 2.7-3.1 nM and high water solubility, thus holding great potential for applications in biological systems.