4.8 Article

Fabrication of NiCo2-Anchored Graphene Nanosheets by Liquid Phase Exfoliation for Excellent Microwave Absorbers

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 14, Pages 12673-12679

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b16144

Keywords

graphene nanosheets; liquid phase exfoliation; NiCo2; single-mode microwave-assisted hydrothermal; permittivity; microwave absorption; reflection loss; quarter-wavelength matching model

Funding

  1. National Natural Science Foundation of China [51271214, 51102206, 51421091, 51571172, 11404280]
  2. National Science Fund for Distinguished Young Scholars [51025103]
  3. Program for New Century Excellent Talents in University [NCET-13-0993]

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Graphene nanosheets (GNSs) were prepared by an efficient liquid-phase,exfoliation method, and then the NiCo2/GNS nanohybrids were fabricated using the-single-mode microwave-assisted hydrothermal- technique. The NiCo2/GNS composites with different GNS proportions were investigated as microwave absorbers. Morphology investigation suggested that NiCo2 nanocrystals were uniformly anchored on the GNS without aggregation. The electromagnetic parameters of NiCo2/GNS nanohybrids could be artificially adjusted by changing the GNS proportion) which led to an exceptional microwave-absorbing performance. A reflection loss (RL) exceeding 20 dB was obtained in the frequency range of 5.3-16.4 GHz for the absorber thicknesses of 1.2-3.2 mm, while an optimal RL of 30 dB was achieved at 11.7 GHz for a thickness of 1.6 mm. The enhanced microwave-absorbing performance indicated that the NiCo2/10 wt % GNS composite has great potential for use as an excellent microwave absorber.

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