Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 26, Pages 5712-5715Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500933
Keywords
C-H activation; Carbonylation; Palladium; Nitrogen heterocycles; Nitroalkenes
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Funding
- Ministero dell'Universita e della Ricerca (MIUR)
- University of Milano
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An efficient catalytic cyclization of -nitrostyrenes to indoles was developed. The reaction was applied to the synthesis of 3-arylindoles and 2-alkylindoles. Given that in the latter case the starting -nitrostyrenes can be easily obtained by a Henry reaction, the present method allows indoles to be obtained in a two-step sequence starting from cheap reactants.
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