4.7 Article

Preparation of hierarchical core-shell C@NiCo2O4@Fe3O4 composites for enhanced microwave absorption performance

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 314, Issue -, Pages 477-487

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2016.12.005

Keywords

Microwave absorption; NiCo2O4; Void space; Multi-reflection

Funding

  1. Qingdao Innovation Leading Talent Program
  2. NSF of China [51173087]
  3. Qingdao Postdoctoral Application Research Project [40601060003]
  4. Taishan Scholars Program

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To obtain excellent microwave absorption (MA) performance, elaborately designing dielectric-magnetic hierarchical C@NiCo2O4@Fe3O4 composites were successfully synthesized by a two-step route. Both the sea urchin-like structure generated by NiCo2O4 and the void space in the core originated from the decomposition of carbon spheres were beneficial structural characteristics for the attenuation of electromagnetic waves. The impedance matching as a result of the addition of uniformly Fe3O4 nanoparticles was a strong contributor to the excellent MA property of C@NiCo2O4@Fe3O4 composites. The minimum reflection loss (RL) value of it reached -43.0 dB at 13.4 GHz with a thickness of 3.4 mm, which Was much higher than that of C@NiCo2O4 or pure NiCo2O4. (C) 2016 Elsevier B.V. All rights reserved.

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