Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 30, Pages 4242-4245Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc01921a
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Funding
- ENEOS Hydrogen Trust Fund
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Covalent organic frameworks are designed to have backbones with different yet discrete contents of triarylamine units that interact weakly with CO2. Adsorption experiments indicate that the triarylamine units dominate the CO2 adsorption process and the CO2 uptake increases monotonically with the triarylamine content. These profound collective effects reveal a principle for designing backbones targeting for CO2 capture and separation.
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